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doi:10.22028/D291-29109
Title: | In situ multi-length scale approach to understand the mechanics of soft and rigid binder in composite lithium ion battery electrodes |
Author(s): | Jäckel, Nicolas Dargel, Vadim Shpigel, Netanel Sigalov, Sergey Levi, Mikhael D. Daikhin, Leonid Aurbach, Doron Presser, Volker |
Language: | English |
Title: | Journal of power sources : the international journal on the science and technology of electrochemical energy systems |
Volume: | 371 |
Startpage: | 162 |
Endpage: | 166 |
Publisher/Platform: | Elsevier |
Year of Publication: | 2017 |
Publikation type: | Journal Article |
Abstract: | Intercalation-induced dimensional changes of composite battery electrodes containing either a stiff or a soft polymeric binder is one of the many factors determining the cycling performance and ageing. Herein, we report dimensional changes in bulk composite electrodes by in situ electrochemical dilatometry (eD) combined with electrochemical quartz-crystal microbalance with dissipation monitoring (EQCM-D). The latter tracks the mechanical properties on the level of the electrode particle size. Lithium iron phosphate (LiFePO4, LFP) electrodes with a stiff binder (PVdF) and a soft binder (NaCMC) were investigated by cycling in lithium sulfate (Li2SO4) aqueous solution. The electrochemical and mechanical electrode performances depend on the electrode cycling history. Based on combined eD and EQCM-D measurements we provide evidence which properties are preferred for a binder used for a composite Li-ion battery electrode. |
DOI of the first publication: | 10.1016/j.jpowsour.2017.10.048 |
URL of the first publication: | https://www.sciencedirect.com/science/article/abs/pii/S0378775317313915 |
Link to this record: | hdl:20.500.11880/28052 http://dx.doi.org/10.22028/D291-29109 |
ISSN: | 0378-7753 1873-2755 |
Date of registration: | 10-Oct-2019 |
Faculty: | NT - Naturwissenschaftlich- Technische Fakultät |
Department: | NT - Materialwissenschaft und Werkstofftechnik |
Professorship: | NT - Prof. Dr. Volker Presser |
Collections: | SciDok - Der Wissenschaftsserver der Universität des Saarlandes |
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