Photochromic organic-inorganic nanocomposites as holograpahic storage media

Abstract

This paper describes the properties of some new organic-inorganic photochromic layers. They are based on a hybrid organic-inorganic matrix in which tungsten heteropolyoxometallates (SiW12O404-, PW12O403-) are entrapped in a network obtained from the reaction of 3-glycidoxy-propyltrimethoxysilane. The high homogeneity of these materials on the nanoscale leads to transparent monoliths and layers of controlled thicknesses up to 40 µm. The optical properties of the blend are emphasised and the construction of amplitude gratings in the materials by two-wave-mixing experiments is described. The results of the optical experiments and the comparison with the theoretical background are used as a model for photochromic holographic storage processes.